The Scorpion star wore a cut-out striped dress, which showed off her killer figure to perfection, with black sandals and her hair pulled back into a slick pony-tail.
The dress was designed by Balmain Paris, and Katharine certainly looked beautiful in it.
Scorpion sadly didn't take home the Favourite TV Drama prize, as Marvel's The Flash was announced the winner on Wednesday night.
The gorgeous brunette - who plays Paige Dineen in the popular drama - was spotted back in November filming new scenes for the show.
Katharine's co-star and boyfriend Elyes Gabel plays the lead role of Walter O'Brian.
She filed for divorce from her estranged husband Nick Cokas in May after being caught kissing married Smash director Michael Morris a year ago.
However, she insisted that she and Nick were separated at the time the photos were taken.
Elyes is most well known for his role in Game Of Thrones but will soon be seen on the big screen in A Most Violent Year opposite Jessica Chastain and Oscar Isaac.
The British actor will also appear in the upcoming Spooks film which sees Kit Harington taking the leading role.
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